The Nations League quarter-finals will see European champions Spain face the Netherlands while Italy play Germany.
Croatia play France in a repeat of the 2018 World Cup final, while Denmark play Portugal in the fourth tie next year.
The games will take place over two legs in March 2025, with the semi-finals and final held in June.
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Spain are the defending champions, beating Croatia on penalties in the summer of 2023.
France won in 2021, and Portugal won the inaugural title back in 2019.
Scotland will play Greece for the chance to stay in League A, while the Republic of Ireland play Bulgaria in the League B/C play-offs.